Low Saponification PVOH LW Series

Low Saponification PVOH LW Series: Information

GOHSENX™ LW Series (aqueous solution type)

The product is an aqueous solution type PVOH with low saponification that has hydrophilic and alcoholphilic properties.
Low saponification PVOHs (35 to 60 mol% saponification) have been used in various applications including hot melt resins, dispersing auxiliaries for suspension polymerization of vinyl chloride, adhesives, coating agents, binders, and pressure sensitive adhesives. However, because the low saponification PVOHs above are usually water insoluble, handling of the resin and application development have been constrained. In contrast, GOHSENX™ LW can be handled in the form of an aqueous solution while maintaining the hydrophobicity characteristic of low saponification PVOHs.

Structural formula

Properties

・Can be handled in the form of an aqueous solution under high concentration conditions (precipitates in a low concentration aqueous solution)
・Maintains the lipophilicity (alcoholphilicity) of low saponification PVOH

Grades and technical specifications

GradeSaponification Value
(mol %)
Viscosity 
(mPa・s)
Product FormApplications
LW-10039.0~46.0500~2,50039 – 41% aqueous solutionDispersing auxiliary for suspension polymerization of vinyl chloride
Adhesives
Binder
Anchor coating agent
LW-20046.0~53.0500~2,000

Viscosity measured in 39–41% aqueous solution at 25°C

Solubility / Liquid Absorption Properties

GOHSENX™ LW products have both a hydrophilic and hydrophobic portion in their molecular structure. They dissolve in or absorb water, as well as various polar organic solvents such as methanol, ethanol, acetone, ethylene glycol, DMSO, and trichloroethylene.

Solubility / liquid absorption properties of GOHSENX™ LW

SolventSolvent Solubility ParameterDissolubility/liquid Absorption Property
(cal/cm3)1/2LW-100LW-200
n-hexane7.423××
Cyclohexane8.182××
1,1,1-trichloroethane8.544××
Toluene8.907××
Methyl ethyl ketone9.038
Cyclohexanone9.255
Tetrahydrofuran9.317
Trichloroethylene9.35
Acetone9.712
1,2-dichloroethane9.91
Pyridine10.58
Acetonitrile11.8
Ethanol12.9
DMSO13
Methanol14.5
Ethylene glycol14.5

◎: Completely dissolved, ○: Almost dissolved, ×: Almost no liquid absorption

Glass transition temperature (Tg) of GOHSENX™ LW

品種Saponification Value
(mol%)
Tg(℃) *1
(Dry)
Tm(℃)*1
LW-10043.1-0.5未検出
Standard PVOH47.342.9未検出

(1) Measuring conditions: Measured with DSC (temp. increase/decrease rate: 10°C/min)

GOHSENX™ LW effluent water load

PolymerCO DBO D
(㎎/㎏)×10⁴(㎎/㎏)×10²
GOHSENX™ T-33080110
GOHSENOL60~10050~100

(1) Measuring conditions: COD (Mw) JIS K0102-17 (1998), BOD5 JIS K0102-21/32.3 (1998)
(2)Measurement: Registration No. of measurement certification business: Osaka No. 10013, KK Osaka Environmental Technology Center